Effect of Polyurethane on the Structure and solubility of Gypsum Soil

Authors

  • Atheer G. Ibrahim National Center for Water Resources Management - Ministry of Water Resources
  • Maysam Th. Al-Hadidi Water Resources Engineering Department, University of Baghdad, Baghdad, Iraq

Keywords:

XRD, XRF, SEM, Gypsum soil, Polyurethane.

Abstract

Gypsum soil is a problematic soil when its gypsum particles are contact with water. The objective of the research is studying the effect of adding polyurethane on the structure of the gypsum soil. This study is continuing to a previous study which explain the process of the treating gypsum soil that subject to water flow in a flume in an experimental canal. The samples of this study have been taken for testing them which stored for four years since 2018, along this period the samples were stored in a room temperature. In this study, these samples subjected to XRD, XRF, and SEM tests to explain the structure of the soil, before and after the treatment. The gypsum content test is done and the results are 41%. The results of XRD test proved that there was low effect of gypsum in the treated soil which have low gypsum index at 2-Thata value due to presence of polyurethane, while the results of XRF test explained that the concentration of elements in treated soil is greater than untreated soil and the reduction in concentrations of the elements Fe, Ca, K, S, and Zn are 83%, 32%, 54%, 85%, and 95%, respectively. In SEM test, the results showed that the gypsum soil became more cohesive due to the addition of the polymer material specially at the zoom 1.00 and 5.00 Kx.

References

Ahmed, A., Kobayashi, M., and Ugai, K. ,2012,Performance assessment of clay soil stabilized with recycled gypsum based on SEM and XRD. In 2nd International Conference on Transportation Geotechnics (ICTG) International Society of Soil Mechanics and Geotechnical Engineering (ISSMGE).‏

Ahmed, B. A., Al-Hadidi, M. T., and Mohammed, D. W, 2020, Improvement of the Gypseous soil properties by using Copolymer and Styrene-butadiene rubber. In IOP Conference Series: Materials Science and Engineering (Vol. 737, No. 1, p. 012084). IOP Publishing.‏

Al-Barrak, K., and Rowell, D. L. ,2006, The solubility of gypsum in calcareous soils. Geoderma, 136(3-4), 830-837.‏

Al-Hadidi, M. T., and Ibrahim, A. G. ,2018, Improvement of Gypsum Soil by Using Polyurethane to Reduce Erosion and Solubility of Irrigation Canals. International Journal of Engineering and Technology, 7(4.20), 372-376.‏

Al-Jassim, W. S., and Al-Hadidi, M. T. ,2020, Impact of rationing on the properties of cement-treated gypsum canals. Association of Arab Universities Journal of Engineering Sciences, 27(3), 15-30.‏

Al-Nedawi, N. M. and Al-Hadidi, M. T. ,2020, Finite element analysis of seepage for Hemrin earth dam using Geo-Studio software. Diyala Journal of Engineering Sciences, 66-76.‏

Buck, B. J., and Van Hoesen, J. G. ,2002, Snowball morphology and SEM analysis of pedogenic gypsum, southern New Mexico, USA. Journal of Arid Environments, 51(4), 469-487.‏

Collin, J. P., & Courtois, B. (1988). Device testing and SEM testing tools. In Testing and Diagnosis of VLSI and ULSI (pp. 469-506). Dordrecht: Springer Netherlands.‏

Danoosh, A. H., and Al-Hadidi, M. T. ,2022, Numerical simulation to the effect of applying rationing system on the stability of the Earth canal: Birmana canal in Iraq as a case study. Journal of the Mechanical Behavior of Materials, 31(1), 729-738.‏

Ebailila, M., Kinuthia, J., and Oti, J. ,2022, Role of gypsum content on the long-term performance of lime-stabilised soil. Materials, 15(15), 5099.‏

Harris, W. I. L. L. I. E., and Norman White, G. ,2008, X‐ray diffraction techniques for soil mineral identification. Methods of soil analysis part 5—Mineralogical methods, 5, 81-115.‏

Ibrahim, A. G., Al-Hadidi, M. T., Hussien, H. H., and Neamah, N. K. ,2022, A Review Study on Gypseous Soils Stabilized with Different Additives in Iraq. Journal of Water Resources and Geosciences, 1(1), 125-141.‏

Jha, A. K., and Sivapullaiah, P. V. ,2014, Role of gypsum on microstructure and strength of soil. Environmental Geotechnics, 3(2), 78-89.‏

Kordlaghari, M. P., and Rowell, D. L. ,2006, The role of gypsum in the reactions of phosphate with soils. Geoderma, 132(1-2), 105-115.‏

Toma, N. M., and Al-Hadidi, M. T. ,2022, The effect of soaking and wetting on the properties of the gypsum soil treated with polyurethane. Association of Arab Universities Journal of Engineering Sciences, 29(2), 01-08.‏

Vermaa, D., Singhb, V., and Kishwanc, J. ,2016, Material conservation–an approach to prevention of pollution. Octa Journal of Environmental Research, 4(4), 312-318.

Weindorf, D. C., Zhu, Y., Ferrell, R., Rolong, N., Barnett, T., Allen, B. L., and Hudnall, W. ,2009, Evaluation of portable X-ray fluorescence for gypsum quantification in soils. Soil science, 174(10), 556-562.‏

Wu, C. M., Tsai, H. T., Yang, K. H., and Wen, J. C. ,2012, How reliable is X-ray fluorescence (XRF) measurement for different metals in soil contamination. Environmental Forensics, 13(2), 110-121.‏

Yilmaz, I., and Civelekoglu, B. ,2009, Gypsum: an additive for stabilization of swelling clay soils. Applied clay science, 44(1-2), 166-172.‏

Published

2024-03-27

How to Cite

Ibrahim, A. G. ., & Al-Hadidi, M. T. . (2024). Effect of Polyurethane on the Structure and solubility of Gypsum Soil. Journal of Water Resources and Geosciences, 3(1), 98–115. Retrieved from https://jwrg.gov.iq/index.php/jwrg/article/view/95